Which of the following reactions does not give a primary amine as a product?

  • A
    $CH_3CH_2CN \xrightarrow{Na/C_2H_5OH} CH_3CH_2CH_2NH_2$
  • B
    $CH_3CONH_2 \xrightarrow{LiAlH_4} CH_3CH_2NH_2$
  • C
    Phthalimide $\xrightarrow[(ii) CH_3CH_2Br]{(i) KOH}$ $\xrightarrow{(iii) H_2O, \Delta} CH_3CH_2NH_2$
  • D
    $CH_3CH_2NC \xrightarrow{H_2/Pd} CH_3CH_2NHCH_3$

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Arrange the following in increasing order of their basic strength:
$(i)$ $C_2H_5NH_2, C_6H_5NH_2, NH_3, C_6H_5CH_2NH_2$ and $(C_2H_5)_2NH$
$(ii)$ $C_2H_5NH_2, (C_2H_5)_2NH, (C_2H_5)_3N, C_6H_5NH_2$
$(iii)$ $CH_3NH_2, (CH_3)_2NH, (CH_3)_3N, C_6H_5NH_2, C_6H_5CH_2NH_2$

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In the following reaction,
$C_6H_5NHCOC_6H_5 \xrightarrow[conc. \ H_2SO_4]{conc. \ HNO_3} X$
the structure of the major product $X$ is

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The increasing order of $pK_b$ for the following compounds will be:
$(A)$ $NH_2-CH=NH$
$(B)$ $1,5,7-Triazabicyclo[4.4.0]dec-5-ene$
$(C)$ $(CH_3)_2NH$

Which of the following statements is incorrect?

Nitrobenzene gives $N$-phenylhydroxylamine by

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